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Gold catalysts for the liquid phase oxidation of o-hydroxybenzyl alcohol

2001; Elsevier BV; Volume: 211; Issue: 2 Linguagem: Inglês

10.1016/s0926-860x(00)00875-9

1873-3875

Candida Milone, R. Ingoglia, G. Neri, Alessandro Pistone, S. Galvagno,

Electrocatalysts for Energy Conversion

Gold on iron oxide catalysts have been investigated in the liquid phase oxidation of o-hydroxybenzylalcohol (salicylic alcohol) under mild conditions. The presence of gold strongly enhances the catalytic activity of iron oxide, which is practically inactive under the same reaction conditions. The liquid phase oxidation of salicylic alcohol follows a first order reaction rate law with respect to the organic substrate. The order of reaction with respect to the oxygen partial pressure is close to zero. The catalytic activity increases with the gold loading. The oxidation of salicylic alcohol on the catalysts with low gold loading leads to the formation of salicylic aldehyde as the main reaction product. A small amount of salicylic acid was also obtained. On the catalysts with higher gold loading a progressive decrease of the yield to salycilic aldehyde with the conversion level occurs. When the reaction is carried out using benzene as solvent, the salycilic aldehyde is the end products on all the catalysts investigated regardless of the gold content.