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Pyrolysis–gas chromatography mass spectrometry and field ionization mass spectrometry of polyquinones

1989; Wiley; Volume: 27; Issue: 3 Linguagem: Inglês

10.1002/pola.1989.080270325

1099-0518

Marianne Blazsó, Emma Jakab, Tamás Székely, Bernd Plage, Hans-Rolf Schulten,

Ion-surface interactions and analysis

Abstract Low‐ and high‐molecular mass thermal decomposition products of five polyquinones with different linking aromatic structures have been analyzed by pyrolysis–gas chromatography and by direct (in‐source) pyrolysis–field ionization mass spectrometry. The quantity of carboxyl groups present in the polymer is obtained by the amounts of carbon dioxide found by pyrolysis–gas chromatography. Assuming a radical thermal decomposition mechanism the distribution of ketoacidic and quinonoid segments along the macromolecular ladder could be estimated from the high‐molecular mass products measured by pyrolysis–field ionization mass spectrometry. A random distribution of the two different segments was found for polyquinones with biphenylene and dibenzofuran subunits, while a structure built up of blocks of two or more identical segments was obtained for polyquinones with dibenzothiophene and diphenylmethane subunits. At the same time the anomalous structural moieties in the polyquinone ladders are also clarified with the help of the identification of the unexpected pyroysis products. Oxidated and bis‐dibenzothiophene and bis‐diphenylmethane subunits were found. The observed temperature dependence for the appearances of the thermal degradation products indicates that condensation and elimination reactions are taking place under the described pyrolysis conditions. Condensation in the ketoacidic segments forming new quinonoid segments proved to be important in the polymer which was a 100% poly(ketoacid), but negligible in the polyquinones containing ketoacidic segments up to 60%.