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Die Rolle der Hydrothermalsynthese in der präparativen Chemie

1985; Wiley; Volume: 97; Issue: 12 Linguagem: Alemão

10.1002/ange.19850971205

1521-3757

A. Rabenau,

Zeolite Catalysis and Synthesis

Angewandte ChemieVolume 97, Issue 12 p. 1017-1032 Aufsatz Die Rolle der Hydrothermalsynthese in der präparativen Chemie Prof. Dr. Albrecht Rabenau, Prof. Dr. Albrecht Rabenau Max-Planck-Institut für Festkörperforschung Heisenbergstraße 1, D-7000 Stuttgart 80Search for more papers by this author Prof. Dr. Albrecht Rabenau, Prof. Dr. Albrecht Rabenau Max-Planck-Institut für Festkörperforschung Heisenbergstraße 1, D-7000 Stuttgart 80Search for more papers by this author First published: Dezember 1985 https://doi.org/10.1002/ange.19850971205Citations: 90AboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract Unter Hydrothermalsynthesen versteht man heute heterogene Reaktionen in wäßrigem Medium oberhalb 100°C und 1 bar. Die früher übliche Unterscheidung zwischen hydrothermalen und pneumatolytischen Bedingungen (unterhalb bzw. oberhalb des kritischen Punktes) wird nicht mehr gemacht, da beim überschreiten kritischer Punkte keine Diskontinuitäten beobachtet werden. Unter hydrothermalen Bedingungen gehen sonst schwerlösliche Stoffe als Komplexe in Lösung, an deren Bildung Wasser selbst oder gut lösliche "Mineralisatoren"︁ beteiligt sein können. Dabei gelten die Gesetzmäßigkeiten chemischer Transportreaktionen, als deren Spezialfall die Hydrothermalsynthese angesehen werden kann. In den letzten Dekaden hat die Methode in den Geowissenschaften – in denen sie auch historisch angesiedelt ist – starke Impulse erfahren, deren übertragung auf die präparative Festkörperchemie diskutiert wird. References 1 H. 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