Charge transfer reactions in near IR absorbing small molecule solution processed organic bulk-heterojunction solar
2010; Elsevier BV; Volume: 12; Issue: 2 Linguagem: Inglês
10.1016/j.orgel.2010.11.014
ISSN1878-5530
AutoresAntonio Sánchez‐Díaz, Roberto Pacios, Udane Muñecas, Tomás Torres⊗, Emilio Palomares,
Tópico(s)Perovskite Materials and Applications
ResumoWe have measured the charge transfer processes on near IR small molecule solution processes solar cells under working conditions. The results show that there are two different behavior, for the device under working conditions, controlled by the intrinsic properties of the organic bulk-heterojunction phase to store charges at the different organic materials. Furthermore, our recombination kinetic studies show the origin of the photovoltage on these thin organic devices (80 nm thick) and the reason for the difference between the observed open circuit cell potential and the theoretical expected value based on the LUMOPCBM–HOMO phthalocyanine difference.
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