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BIBTEX RIS

A Study of the Atherton–Todd Reaction Mechanism

1990; Oxford University Press; Volume: 63; Issue: 4 Linguagem: Inglês

10.1246/bcsj.63.1284

ISSN

1348-0634

Autores

K. Troev, Emil Kirilov, D. Max Roundhill,

Tópico(s)

Molecular spectroscopy and chirality

Resumo

Abstract It has been shown that alkylammonium methyl phosphonates [CH3OP(O)HO]− [NCH3R3]+ and sodium ethyl phosphonate [CH3CH2OP(O)HO]− Na+ catalyse the Atherton–Todd reaction. It has been established that the alkylammonium salts themself react with carbon tetrachloride to give chloroform, resulting in the postulate that base activation leads to the monoalkyl phosphonate anion.

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