Revised Structure of the Fungal Germination Self‐Inhibitor Gloeosporone
1987; Wiley; Volume: 70; Issue: 2 Linguagem: Inglês
10.1002/hlca.19870700203
ISSN1522-2675
AutoresWalter L. Meyer, W. Bernd Schweizer, Albert K. Beck, Werner Scheifele, Dieter Seebàch, Stuart L. Schreiber, Sarah E. Kelly,
Tópico(s)Fungal Biology and Applications
ResumoAbstract Gloeosporone, the germination self‐inhibitor from the fungus Colletotrichum gloeosporioides f.sp. jussiaea , is shown by spectroscopic data and X‐ray analysis to have the constitution and relative configuration as shown in Formula 2 (either (1 S ,6 R ,12 R )‐1‐hydroxy‐6‐pentyl‐5,15‐dioxabicyclo[10.2.1]pentadecan‐4,13‐dione or its enantiomer), rather than the previously assigned constitution 1 .
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