Intrinsic single-band upconversion emission in colloidal Yb/Er(Tm):Na3Zr(Hf)F7 nanocrystals
2012; Royal Society of Chemistry; Volume: 48; Issue: 86 Linguagem: Inglês
10.1039/c2cc35480b
ISSN1364-548X
AutoresDaqin Chen, Lei Lei, Rui Zhang, Anping Yang, Ju Xu, Yuansheng Wang,
Tópico(s)Radiation Detection and Scintillator Technologies
ResumoNovel Yb/Er(Tm):Na3MF7 (M = Zr, Hf) nanocrystals with intrinsic single-band upconversion emission, in contrast to the routine lanthanide-doped fluoride nanocrystals which show typical multi-band upconversion emissions, are reported for the first time. Specifically, the red upconversion intensity of the Yb/Er:Na3ZrF7 nanocrystals is about 5 times as high as that of the hexagonal Yb/Er:NaYF4 ones with a similar crystal size.
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