Synthesis and Characterization of New Binuclear Co(0) Complexes with Diphosphinoamine Ligands. A Potential Approach for Asymmetric Pauson−Khand Reactions
1999; American Chemical Society; Volume: 64; Issue: 10 Linguagem: Inglês
10.1021/jo982245o
ISSN1520-6904
AutoresYves Gimbert, Frédéric Robert, A. Durif, Marie-Thérèse Averbuch, Nina Kann, Andrew E. Greene,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoThe synthesis of P-N-P bidentate ligands and the evaluation, based on IR and X-ray data, of their pi-acceptor properties in the complexes derived from phenylacetylene-dicobalt hexacarbonyl have been carried out. In addition, the reactivity of these complexes in the Pauson-Khand reaction has been examined.
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