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Thermal Splitting of Bis-Cu(II) Octaphyrin(1.1.1.1.1.1.1.1) into Two Cu(II) Porphyrins

2004; American Chemical Society; Volume: 126; Issue: 10 Linguagem: Inglês

10.1021/ja031935t

1943-2984

Yasuo Tanaka, W. Hoshino, Soji Shimizu, K. Youfu, Naoki Aratani, Norihiko Maruyama, Shizυo Fujita, Atsuhiro Osuka,

Magnetism in coordination complexes

When heated, bis-Cu(II) octaphyrin(1.1.1.1.1.1.1.1) is quantitatively split into two Cu(II) porphyrins both in solution and film states, which is accompanied by large absorption spectral changes.