Methods for the determination of limit of detection and limit of quantitation of the analytical methods

2011; Medknow; Volume: 2; Issue: 1 Linguagem: Inglês

10.4103/2229-5186.79345

ISSN

2229-5186

Autores

Alankar Shrivastava, VipinB Gupta,

Tópico(s)

Pesticide Residue Analysis and Safety

Resumo

The quality of an analytical method developed is always appraised in terms of suitability for its intended purpose, recovery, requirement for standardization, sensitivity, analyte stability, ease of analysis, skill subset required, time and cost in that order. It is highly imperative to establish through a systematic process that the analytical method under question is acceptable for its intended purpose. Limit of detection (LOD) and limit of quantification (LOQ) are two important performance characteristics in method validation. LOD and LOQ are terms used to describe the smallest concentration of an analyte that can be reliably measured by an analytical procedure. There has often been a lack of agreement within the clinical laboratory field as to the terminology best suited to describe this parameter. Likewise, there have been various methods for estimating it. The presented review provides information relating to the calculation of the limit of detection and limit of quantitation. Brief information about differences in various regulatory agencies about these parameters is also presented here.

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