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Influence of the substitution pattern on the optoelectronic properties of oligofuran and oligothiophene–phosphole chains

2012; Elsevier BV; Volume: 730; Linguagem: Inglês

10.1016/j.jorganchem.2012.08.032

1872-8561

Ngoc Hoa Tran Huy, Yunpeng Lu, Lloyd F. N. Ah Qune, François Mathey,

Organic Light-Emitting Diodes Research

2-α-Terthienyl- and terfuryl-1,3,4-trimethylphospholes were prepared by [1,5] shift of the terthienyl or terfuryl substituents from P to the α-carbon of the ring in the appropriate 1-terthienyl- or terfurylphospholes under heating in basic medium, followed by quenching the resulting phospholides by methyl iodide. The corresponding sulfide, borane and gold iodide complexes were prepared in the terthienyl case. Comparing the spectra of the highly fluorescent borane complexes of the 2-terfuryl and 2-terthienyl-phospholes showed that the UV–Vis absorption wavelength is not significantly modified upon replacement of S by O but that the fluorescence quantum yield is multiplied by 1.82.