Infrared spectrum of cyclopropylamine
1988; Elsevier BV; Volume: 125; Issue: 1 Linguagem: Inglês
10.1016/0301-0104(88)85005-5
ISSN1873-4421
AutoresYoshiaki Hamada, Masamichi Tsuboi, Izuho Ikeda, Munetaka Nakata, Mitsuo Tasumi,
Tópico(s)Spectroscopy and Laser Applications
ResumoThe previously reported vibrational assignments of the fundamental bands of cyclopropylamine which are observed between 1300 and 750 cm−1 are revised. The new assignments are based on the infrared absorption spectra of the normal and N-deuterated species in the gas phase and in Ar-matrix in combination with the existing Raman data. The assignments are also supported by comparing with the results of an ab initio MO calculation. The abundance ratio of two rotational isomers is discussed.
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