A New In 4 Cluster with Short InIn Bonds in Trigonal‐Planar In(InTrip 2 ) 3
1996; Wiley; Volume: 35; Issue: 20 Linguagem: Inglês
10.1002/anie.199623551
ISSN1521-3773
AutoresPenelope J. Brothers, K. Hübler, Ute Hübler, B.C. Noll, Marilyn M. Olmstead, Philip P. Power,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoAngewandte Chemie International Edition in EnglishVolume 35, Issue 20 p. 2355-2357 Communication A New In4 Cluster with Short InIn Bonds in Trigonal-Planar In(InTrip2)3† Dr. Penelope J. Brothers, Corresponding Author Dr. Penelope J. Brothers Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected] Penelope J. Brothers, Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected] Philip P. Power, Department of Chemistry, University of California Davis, CA 95616 (USA)Search for more papers by this authorDr. Klaus Hübler, Dr. Klaus Hübler Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected]Search for more papers by this authorDr. Ute Hübler, Dr. Ute Hübler Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected]Search for more papers by this authorDr. Bruce C. Noll, Dr. Bruce C. Noll Department of Chemistry, University of California Davis, CA 95616 (USA)Search for more papers by this authorDr. Marilyn M. Olmstead, Dr. Marilyn M. Olmstead Department of Chemistry, University of California Davis, CA 95616 (USA)Search for more papers by this authorProf. Philip P. Power, Corresponding Author Prof. Philip P. Power Department of Chemistry, University of California Davis, CA 95616 (USA) Penelope J. Brothers, Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected] Philip P. Power, Department of Chemistry, University of California Davis, CA 95616 (USA)Search for more papers by this author Dr. Penelope J. Brothers, Corresponding Author Dr. Penelope J. Brothers Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected] Penelope J. Brothers, Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected] Philip P. Power, Department of Chemistry, University of California Davis, CA 95616 (USA)Search for more papers by this authorDr. Klaus Hübler, Dr. Klaus Hübler Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected]Search for more papers by this authorDr. Ute Hübler, Dr. Ute Hübler Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected]Search for more papers by this authorDr. Bruce C. Noll, Dr. Bruce C. Noll Department of Chemistry, University of California Davis, CA 95616 (USA)Search for more papers by this authorDr. Marilyn M. Olmstead, Dr. Marilyn M. Olmstead Department of Chemistry, University of California Davis, CA 95616 (USA)Search for more papers by this authorProf. Philip P. Power, Corresponding Author Prof. Philip P. Power Department of Chemistry, University of California Davis, CA 95616 (USA) Penelope J. Brothers, Department of Chemistry, University of Auckland Private Bag 92019, Auckland (New Zealand) Fax: Int. code +9 373 7422 email: [email protected] Philip P. Power, Department of Chemistry, University of California Davis, CA 95616 (USA)Search for more papers by this author First published: November 1, 1996 https://doi.org/10.1002/anie.199623551Citations: 49 † This work was supported by the National Science Foundation. P. J. B. thanks the University of Auckland for granting sabbatical leave and K. H. thanks the Alexander von Humboldt Foundation (Lynen Fellowship). AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Trigonal-planar coordination is seen for the indium center in In(InTrip2)3 (1) (Trip 2,4,6-iPr3C6H2), the first indane with three unusually short bonds to indium substituents. The compound is obtained by the reduction of the diindane Trip2InInTrip2 with lithium metal. In contrast, reduction of the aluminum and gallium analogs gives the [Trip2MMTrip2]− anions, which have a MM π-bond order of 0.5. Citing Literature Volume35, Issue20November 1, 1996Pages 2355-2357 RelatedInformation
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