Reactivity of η 5 ‐Indenylrhodium ( I ) Complexes; Cyclocotrimerization of Alkynes with Alkenes
1977; Wiley; Volume: 16; Issue: 9 Linguagem: Inglês
10.1002/anie.197706481
ISSN1521-3773
AutoresPeter Caddy, Michael Green, Edmund O'Brien, Lesley E. Smart, Peter Woodward,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoIndenyl-and cyclopentadienylrhodium(I) complexes have somewhat different properties. Observations on indenyl complexes (ligands not shown) suggest the following reaction course for cyclocotrimerization of alkynes with alkenes:
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