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Formation and characterization of neutral and cationic amino(thio)carbene complexes of gold(I) from thiazolyl precursors

1994; Royal Society of Chemistry; Issue: 14 Linguagem: Inglês

10.1039/dt9940002091

2050-5671

H.G. Raubenheimer, Fred Scott, Gert J. Kruger, James G. Toerien, R. Otte, Werner E. van Zyl, Itha Taljaard, Pierre J. Olivier, Lorna Linford,

N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Benzothiazole-2-yl-, 4-methylthiazolyl- and thiazolyl-lithium reacted with [AuCl(tht)](tht = tetrahydrothiophene) to form bis(thiazolyl)aurate compounds which can be protonated or alkylated to give mono- and bis-(carbene) complexes of the type [Au([graphic omitted])([graphic omitted])] and [Au(CNRCX1= CX2S)2]+(X1X2= C4H4; X1= Me, X2= H; X1= X2= H; R = H or Me). The strongly ligated gold phosphine and perfluorophenyl complexes [AuCl(PPh3)] and [Au(C6F5)(tht)] as well as AuCN also reacted with the thiazolyllithiums to afford, upon protonation or alkylation, cationic and neutral carbene compounds. Complicating side-reactions, such as homoleptic rearrangement, protonation or alkylation on carbon rather than nitrogen and dissociative polymerization were observed. The crystal structure of the neutral mono(carbene) complex [Au([graphic omitted])([graphic omitted])] shows a gold–gold interaction with a distance of 3.075(1)Å.