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X-ray absorption spectra of the spinel LiCu0.5Mn1.5O4

2007; Elsevier BV; Volume: 175; Issue: 1 Linguagem: Inglês

10.1016/j.jpowsour.2007.09.012

1873-2755

M. Womes, Pierre‐Emmanuel Lippens, B. Léon, C. Vicente, José L. Tirado,

Magnetic and transport properties of perovskites and related materials

Abstract X-ray absorption spectra of the spinel LiCu0.5Mn1.5O4 were recorded at the Cu K and L3, Mn K and L3, and O K edge. The spectra are aligned on a common energy scale with the aim to establish an experimental picture of the conduction band structure. The fine structures observed a few electron volts around the absorption thresholds are discussed in terms of hybridisation of cation and anion orbitals. Emphasis is put on the identification of spectral features correlated with the presence of lithium on the tetrahedral sites of the spinel structure. The consequences of lithium insertion/extraction on the intensities of these spectral structures are discussed. Previous studies by X-ray absorption spectroscopy of lithium insertion/extraction in various spinels are found to agree with our expectations.