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The conformational analysis of saturated heterocycles. Part LVII. Cyclic and acyclic tetra-alkylhydrazines

1974; Royal Society of Chemistry; Issue: 4 Linguagem: Inglês

10.1039/p29740000406

2050-8239

Richard A. Jones, Alan R. Katritzky, Keith A. F. Record, R. Scattergood,

Synthesis and Reactivity of Heterocycles

Equilibrium and kinetic processes in acyclic, cyclic, and polycyclic tetra-alkyltetrazines are discussed with reference both to new and to literature data. A consistent overall picture is presented in terms of 'passing' and 'non-passing' inversion processes which differ in the magnitude of steric hindrance in the transition state.