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Compressions of water + alcohol mixtures at 298.15 K and 1000 atm

1977; Elsevier BV; Volume: 9; Issue: 6 Linguagem: Inglês

10.1016/0021-9614(77)90162-8

1096-3626

Takashi Moriyoshi, Yoshitaka Morishita, Hiroyuki Inubushi,

Chemical Thermodynamics and Molecular Structure

The compressions of binary mixtures of water + methanol, + ethanol, + i-propanol, and + t-butanol have been measured as a function of composition at 298.15 K and 1000 atm. The partial molar volumes of the components at 1 and 1000 atm have been calculated by combination of the experimental values with available densities at 1 atm for each system. The composition dependence of the compressions is explained in terms of the partial compressions of the components.