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OPTICAL CONSTANTS OF NH 3 AND NH 3 :N 2 AMORPHOUS ICES IN THE NEAR-INFRARED AND MID-INFRARED REGIONS

2013; IOP Publishing; Volume: 777; Issue: 1 Linguagem: Inglês

10.1088/0004-637x/777/1/26

1538-4357

Alexandre Zanchet, Y. Rodrı́guez-Lazcano, Óscar Gálvez, Vı́ctor J. Herrero, Rafael Escribano, Belén Maté,

Astro and Planetary Science

Ammonia ice has been detected on different astrophysical media ranging from interstellar medium (ISM) particles to the surface of various icy bodies of our solar system, where nitrogen is also present. We have carried out a detailed study of amorphous NH3 ice and NH3:N2 ice mixtures, based on infrared (IR) spectra in the mid-IR (MIR) and near-IR (NIR) regions, supported by theoretical quantum chemical calculations. Spectra of varying ice thicknesses were obtained and optical constants were calculated for amorphous NH3 at 15 K and 30 K and for a NH3:N2 mixture at 15 K over a 500–7000 cm−1 spectral range. These spectra have improved accuracy over previous data, where available. Moreover, we also obtained absolute values for the band strengths of the more prominent IR features in both spectral regions. Our results indicate that the estimated NH3 concentration in ISM ices should be scaled upward by ∼30%.