The Synthesis of Hexafluorosumanene and Its Congeners
2013; Wiley; Volume: 19; Issue: 10 Linguagem: Inglês
10.1002/chem.201204622
ISSN1521-3765
AutoresBernd M. Schmidt, Berit Topolinski, Shuhei Higashibayashi, Tatsuhiro Kojima, Masaki Kawano, Dieter Lentz, Hidehiro Sakurai,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoChemistry – A European JournalVolume 19, Issue 10 p. 3282-3286 Communication The Synthesis of Hexafluorosumanene and Its Congeners Bernd M. Schmidt, Bernd M. Schmidt Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan) Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstrasse 34-36, 14195 Berlin (Germany)Search for more papers by this authorBerit Topolinski, Berit Topolinski Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan) Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstrasse 34-36, 14195 Berlin (Germany)Search for more papers by this authorDr. Shuhei Higashibayashi, Dr. Shuhei Higashibayashi Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan)Search for more papers by this authorDr. Tatsuhiro Kojima, Dr. Tatsuhiro Kojima Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), San 31 Hyojadong, Pohang 790-784 (South Korea)Search for more papers by this authorProf. Dr. Masaki Kawano, Prof. Dr. Masaki Kawano Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), San 31 Hyojadong, Pohang 790-784 (South Korea)Search for more papers by this authorProf. Dr. Dieter Lentz, Prof. Dr. Dieter Lentz Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstrasse 34-36, 14195 Berlin (Germany)Search for more papers by this authorProf. Dr. Hidehiro Sakurai, Corresponding Author Prof. Dr. Hidehiro Sakurai hsakurai@ims.ac.jp Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan)Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan)Search for more papers by this author Bernd M. Schmidt, Bernd M. Schmidt Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan) Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstrasse 34-36, 14195 Berlin (Germany)Search for more papers by this authorBerit Topolinski, Berit Topolinski Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan) Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstrasse 34-36, 14195 Berlin (Germany)Search for more papers by this authorDr. Shuhei Higashibayashi, Dr. Shuhei Higashibayashi Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan)Search for more papers by this authorDr. Tatsuhiro Kojima, Dr. Tatsuhiro Kojima Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), San 31 Hyojadong, Pohang 790-784 (South Korea)Search for more papers by this authorProf. Dr. Masaki Kawano, Prof. Dr. Masaki Kawano Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), San 31 Hyojadong, Pohang 790-784 (South Korea)Search for more papers by this authorProf. Dr. Dieter Lentz, Prof. Dr. Dieter Lentz Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstrasse 34-36, 14195 Berlin (Germany)Search for more papers by this authorProf. Dr. Hidehiro Sakurai, Corresponding Author Prof. Dr. Hidehiro Sakurai hsakurai@ims.ac.jp Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan)Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan)Search for more papers by this author First published: 10 February 2013 https://doi.org/10.1002/chem.201204622Citations: 25Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description chem_201204622_sm_miscellaneous_information.pdf504.9 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume19, Issue10March 4, 2013Pages 3282-3286 RelatedInformation
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