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Vibrational energy relaxation in CH3X molecules

1980; Elsevier BV; Volume: 73; Issue: 3 Linguagem: Inglês

10.1016/0009-2614(80)80688-9

1873-4448

Joris Schuurman, G. H. Wegdam,

Atmospheric Ozone and Climate

Abstract Opto-acoustic techniques have been used to measure vibiational energy relaxation in methyl halides and their mixtures with inert gases. Under certain conditions time-resolved measurements give direct evidence of a V-R-T relaxation channel parallel to the V-T relaxation channel. Comparison with infrared fluorescence data confirms this conclusion.