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Prussian blue: a new framework of electrode materials for sodium batteries

2012; Royal Society of Chemistry; Volume: 48; Issue: 52 Linguagem: Inglês

10.1039/c2cc31777j

1364-548X

Yuhao Lu, Long Wang, Jinguang Cheng, John B. Goodenough,

Inorganic Chemistry and Materials

Prussian blue and its analogues consisting of different transition-metal ions (Fe, Mn, Ni, Cu, Co and Zn) have been synthesized at room temperature. Insertion of Na into KFe2(CN)6 in a carbonate electrolyte exhibited a reversible capacity near 100 mA h g−1 with no capacity fade in 30 cycles. The data indicate that a Na-ion battery with a Prussian blue framework as a cathode will be feasible.