The structure of the chloro derivative of titanocene, [(C10H3)(C5H5)2Ti2Cl2]
1977; Elsevier BV; Volume: 128; Issue: 3 Linguagem: Inglês
10.1016/s0022-328x(00)92210-1
ISSN1872-8561
Autores Tópico(s)Coordination Chemistry and Organometallics
ResumoThe crystal structure of the chloro derivative of titanocene has been determined by single-crystal X-ray analysis and shown to be [(C10H3)(C5H8)2Ti2Cl2]. Each of the rings of a fulvalene ligand, C5H4C5H4, is π-coordinated to one Ti. Furthermore, each Ti is coordinated by one πC5H5 ligand and by two Cl atoms which bridge the two metal atoms. There is no TiTi bond. The observed diamagnetism of the compound is tentatively ascribed to the coupling of the two metal atoms by the fulvalene ligand.
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