Novel trinuclear palladium(0) complexes; tris(tribenzylideneacetylacetone) tripalladium(solvent) complexes and their reactions
1974; Elsevier BV; Volume: 73; Issue: 3 Linguagem: Inglês
10.1016/s0022-328x(00)83841-3
ISSN1872-8561
AutoresYoshio Ishii, Seiji Hasegawa, Sadao Kimura, Kiminori Itoh,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoIn an extension of our studies on palladium(0)dibenzylideneacetone complexes, novel trinuclear palladium complexes with three molecules of tribenzylideneacetylacetone have been obtained and identified by elemental and spectroscopic analyses (IR, UV and NMR). Ligand exchange reactions, oxidative addition reactions and complex formation reaction with maleic anhydride, dimethyl acetylenedicarboxylate and para-quinones were investigated. These were found to be similar to those of palladium (0)dibenzylideneacetone complexes.
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