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Hydrozirconation: A New Transition Metal Reagent for Organic Synthesis

1976; Wiley; Volume: 15; Issue: 6 Linguagem: Inglês

10.1002/anie.197603331

1521-3773

Jeffrey Schwartz, Jay A. Labinger,

Asymmetric Hydrogenation and Catalysis

Abstract Hydrozirconation has recently been developed as a procedure for functionalizing alkenes, alkynes, and 1,3‐dienes via organozirconium(IV) intermediates. These intermediates react with a variety of electrophilic reagents to give organic products in high yield. Mechanisms of reactions involved in these sequences are discussed.