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Cis-epoxides via sharpless' asymmetric dihydroxylation reaction: Synthesis of (+)-disparlure

1994; Elsevier BV; Volume: 35; Issue: 21 Linguagem: Inglês

10.1016/s0040-4039(00)73251-5

1873-3581

Soo Y. Ko,

Oxidative Organic Chemistry Reactions

(+)-Disparlure, containing an isolated cis-epoxide functional group, was synthesized employing the asymmetric dihydroxylation and cyclic sulfate rearrangement-opening reactions as the key steps.