Manganese(IV) oxamato-catalyzed oxidation of secondary alcohols to ketones by dioxygen and pivalaldehyde
1998; Royal Society of Chemistry; Issue: 9 Linguagem: Inglês
10.1039/a800930i
ISSN1364-548X
AutoresRafael Ruiz‐García, Ally Aukauloo, Yves Journaux, Rafael Ruiz‐García, Ally Aukauloo, Isabel Fernández, José R. Pedro, Antonio L. Roselló, Beatriz Cervera, Isabel Castro, M. Carmen Muñoz,
Tópico(s)Porphyrin and Phthalocyanine Chemistry
ResumoA new manganese(IV) oxamato complex possessing a bis(µ-oxo)dimanganese core has been synthesized, magnetically and structurally characterized, and found to catalyze the aerobic oxidation of secondary alcohols to ketones with co-oxidation of pivalaldehyde to pivalic acid with good yields and high selectivities.
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