Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel
2013; Elsevier BV; Volume: 66; Linguagem: Inglês
10.1016/j.carbon.2013.08.052
ISSN1873-3891
AutoresKung‐Chin Chang, Min‐Hsiang Hsu, Hsin‐I Lu, Mei‐Chun Lai, Pei‐Ju Liu, Chien‐Hua Hsu, Wei-Fu Ji, Tsao‐Li Chuang, Yen Wei, Jui‐Ming Yeh, Wei‐Ren Liu,
Tópico(s)Metal and Thin Film Mechanics
ResumoNanocasting was used to develop epoxy/graphene composites (EGCs) as corrosion inhibitors with hydrophobic surfaces (HEGC). The contact angle of water droplets on a sample surface can be increased from ∼82° (epoxy surface) to ∼127° (hydrophobic epoxy and EGC). It should be noted that EGC coating was found to provide an excellent corrosion protection effect on cold-rolled steel (CRS) electrode. Enhancement of corrosion protection using EGC coatings could be attributed to the following three reasons: (1) epoxy could act as a physical barrier coating, (2) the hydrophobicity repelled the moisture and further reduced the water/corrosive media adsorption on the epoxy surface, preventing the underlying metals from corrosion attack, and (3) the well-dispersed graphene nanosheets (GNSs) embedded in HEGC matrix could prevent corrosion owing to a relatively higher aspect ratio than clay platelets, which enhances the oxygen barrier property of HEGC.
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