Artigo Revisado por pares

Construction of bicyclic systems via a tandem free radical cyclopropylcarbinyl rearrangement-cyclisation strategy

1992; Elsevier BV; Volume: 48; Issue: 37 Linguagem: Inglês

10.1016/s0040-4020(01)80475-0

ISSN

1464-5416

Autores

Robert A. Batey, John D. Harling, William B. Motherwell,

Tópico(s)

Catalytic Cross-Coupling Reactions

Resumo

Regio- and stereospecific construction of bicyclic systems may be achieved by directed Simmons-Smith cyclopropanation of an allylic alcohol possessing a suitably positioned unsaturated acceptor, followed by a tandem free radical cyclopropylcarbinyl rearrangement-cyclisation reaction.

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