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Synthesis of a new endohedral fullerene family, Sc2S@C2n (n = 40–50) by the introduction of SO2

2010; Royal Society of Chemistry; Volume: 46; Issue: 26 Linguagem: Inglês

10.1039/c0cc00835d

1364-548X

Ning Chen, Manuel N. Chaur, Cheryl A. Moore, Julio R. Pinzón, Ramón Valencia, Antonio Rodríguez‐Fortea, Josep M. Poblet, Luís Echegoyen,

Inorganic Chemistry and Materials

By introducing SO2 as the sulfur source, the synthesis of an extensive family of cluster endohedral fullerenes Sc2S@C2n (n = 40–50) was demonstrated and a new isomer of Sc2S@C82 (Cs : 6) was isolated and characterized by spectroscopic and electrochemical methods for the first time.