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Oxidation by Chemical Manganese Dioxide. Part 1. Facile Oxidation of Benzylic Alcohols in Hexane†

1998; Science Reviews Ltd.; Issue: 6 Linguagem: Inglês

10.1039/a709079j

1364-5560

Masao Hirano, Sigetaka Yakabe, Hideki Chikamori, James H. Clark, Tsumoru Morimoto,

Chemical Synthesis and Reactions

An inexpensive, stable, commercially available reagent, chemical manganese dioxide, can be used for the oxidation of a wide variety of benzylic alcohols and the C–C bond cleavage of aromatic diols in hexane under relatively mild conditions.