Complementary short syntheses of (±)-methyl shikimate
1984; Elsevier BV; Volume: 25; Issue: 15 Linguagem: Inglês
10.1016/s0040-4039(01)90029-2
ISSN1873-3581
AutoresMalcolm M. Campbell, Aston D. Kaye, M. Sainsbury, Roya Yavarzadeh,
Tópico(s)Plant biochemistry and biosynthesis
ResumoTwo syntheses of (±)-methyl shikimate from the adduct of furan and methyl acrylate are described. One requires the regioselective hydroxylation of (±)-5β,6β-dihydroxy-O,O-isopropylidene-2-methoxycarbonylcyclohexa-1,3-diene and the other cis-dihydroxylation of (±)-5-hydroxy-1-methoxycarbonylcyclohexa-1,3-diene.
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