PVT Properties of Dinitrogen Monoxide
2004; American Chemical Society; Volume: 49; Issue: 5 Linguagem: Inglês
10.1021/je049842u
ISSN1520-5134
AutoresGiovanni Di Nicola, Giuliano Giuliani, Renato Ricci, Roman Stryjek,
Tópico(s)Photochemistry and Electron Transfer Studies
ResumoThe PVT properties of dinitrogen monoxide (N2O) have been measured. In particular, experiments were performed by means of two different apparatus, both in the two-phase region and in the superheated vapor-phase region: the isochoric method was applied in the saturation region, and the Burnett method was applied in the vapor region. Isochoric measurements were carried out at temperatures from (219 to 273) K and at pressures from (550 to 3100) kPa. The 18 measurements along the saturated liquid−vapor region were fit, together with selected literature data, with the Wagner equation. For Burnett measurements, 14 runs along 7 isotherms in a pressure range from (170 to 5200) kPa were made. The second and third virial coefficients were derived, and good consistency was found after comparison with data in the literature.
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