The Copper(II) Complex with Two Didentate Schiff Base Ligands. The Unique Rearrangment that Proceeds under Alcohol Vapor in the Solid State to Construct Noninclusion Structure
2007; Oxford University Press; Volume: 37; Issue: 1 Linguagem: Inglês
10.1246/cl.2008.78
ISSN1348-0715
AutoresYuhki Shibuya, K. Nabari, Mitsuru Kondo, Sachie Yasue, Kenji Maeda, Fumio Uchida, Hiroyuki Kawaguchi,
Tópico(s)Lanthanide and Transition Metal Complexes
ResumoAbstract The complexation reaction of copper(II) ion and N-(m-hydroxyphenylene)salicylideneaminate (mhsa) in EtOH yields EtOH-inclusion and noninclusion crystalline samples, [Cu(mhsa)2]·2EtOH (1) and [Cu(mhsa)2] (2), respectively. The amorphous sample obtained by drying 1 rearranges to the noninclusion complex 2 under alcohol vapor in the solid state.
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