A zirconium-promoted methylenation of aldehydes, ketones, and enones
1989; Elsevier BV; Volume: 30; Issue: 30 Linguagem: Inglês
10.1016/s0040-4039(00)99286-4
ISSN1873-3581
AutoresJames M. Tour, Peter V. Bedworth, Ruilian Wu,
Tópico(s)Catalytic Cross-Coupling Reactions
ResumoTreatment of zirconocene dichloride with dibromomethane and zinc affords an organometallic intermediate which rapidly methylenates aldehydes, ketones, and enones at room temperature.
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