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SiBr 2 (Idipp): A Stable N‐Heterocyclic Carbene Adduct of Dibromosilylene

2009; Wiley; Volume: 48; Issue: 31 Linguagem: Inglês

10.1002/anie.200902431

1521-3773

Alexander C. Filippou, Oleg Chernov, Gregor Schnakenburg,

Organoboron and organosilicon chemistry

Angewandte Chemie International EditionVolume 48, Issue 31 p. 5687-5690 Communication SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene† Alexander C. Filippou Prof. Dr., Alexander C. Filippou Prof. Dr. filippou@uni-bonn.de Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany), Fax: (+49) 30-735-327Search for more papers by this authorOleg Chernov Dipl.-Chem., Oleg Chernov Dipl.-Chem. Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany), Fax: (+49) 30-735-327Search for more papers by this authorGregor Schnakenburg Dr., Gregor Schnakenburg Dr. Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany), Fax: (+49) 30-735-327Search for more papers by this author Alexander C. Filippou Prof. Dr., Alexander C. Filippou Prof. Dr. filippou@uni-bonn.de Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany), Fax: (+49) 30-735-327Search for more papers by this authorOleg Chernov Dipl.-Chem., Oleg Chernov Dipl.-Chem. Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany), Fax: (+49) 30-735-327Search for more papers by this authorGregor Schnakenburg Dr., Gregor Schnakenburg Dr. Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany), Fax: (+49) 30-735-327Search for more papers by this author First published: 15 July 2009 https://doi.org/10.1002/anie.200902431Citations: 236 † We thank the Deutsche Forschungsgemeinschaft (SFB 813) for the generous financial support of this work. We also thank C. Schmidt, K. Prochnicki, and H. Spitz for recording the solution NMR spectra, Dr. W. Hoffbauer for the solid-state 29Si NMR experiment, and A. Martens for the elemental analyses. Idipp=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Silylene with a carbene carabiner: The synthesis, structure, and some reactions of a stable carbene adduct of dibromosilylene, SiBr2(Idipp) (see picture; Idipp=1,3-bis(2,6-diisopropylphenyl)- imidazol-2-ylidene), are described. SiBr2(Idipp) was characterized by X-ray crystallography, NMR spectroscopy, and theoretical methods. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200902431_sm_miscellaneous_information.pdf242.3 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume48, Issue31July 20, 2009Pages 5687-5690 RelatedInformation