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ASYMMETRIC REDUCTION OF PROCHIRAL KETO ESTERS WITH A CHIRAL REDUCING AGENT PREPARED FROM TIN(II) CHLORIDE, CHIRAL DIAMINE, AND DIISOBUTYLALUMINUM HYDRIDE

1985; Oxford University Press; Volume: 14; Issue: 6 Linguagem: Inglês

10.1246/cl.1985.813

1348-0715

Teruaki Mukaiyama, K. TOMIMORI, Takeshi Oriyama,

Asymmetric Synthesis and Catalysis

Abstract Asymmetric reduction of prochiral keto esters with a reagent, generated by treatment of a mixture of tin(II) chloride and a chiral diamine derived from (S)-proline with diisobutylaluminum hydride, afforded the corresponding optically active hydroxy esters.