Catalytic, high-speed tishchenko reaction using (2,7-dimethyl-1,8-biphenylenedioxy)bis(diisopropoxyaluminum) as a powerful bidentate catalyst
1999; Elsevier BV; Volume: 40; Issue: 43 Linguagem: Inglês
10.1016/s0040-4039(99)01555-5
ISSN1873-3581
AutoresTakashi Ooi, Tomoya Miura, Keisuke Takaya, Keiji Maruoka,
Tópico(s)Asymmetric Synthesis and Catalysis
ResumoExceedingly high-speed Tishchenko reaction of various aldehydes can be realized by using a powerful, bidentate aluminum catalyst. This catalytic system is also applicable to the highly stereoselective intramolecular Tishchenko reduction of β-hydroxy ketones.
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