Intramolecular aromatic 1,5-hydrogen transfer in free radical reactions. II. Rearrangement of iodobenzophenones
1999; Elsevier BV; Volume: 40; Issue: 34 Linguagem: Inglês
10.1016/s0040-4039(99)01292-7
ISSN1873-3581
AutoresJordan M. Cummins, Ulf‐H. Dolling, Alan W. Douglas, Sandor Karady, William R. Leonard, Benjamin Marcune,
Tópico(s)Vanadium and Halogenation Chemistry
ResumoAbstract Products derived from the homolysis of the aromatic CI bond of ortho -iodobenzophenones by photolysis or tributyltin radicals indicate 1,5-hydrogen migration. The reactions include iodine migration, hydrogen abstraction and arylation.
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