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Asymptotic analysis with reduced chemistry for the burning of n-heptane droplets

1992; Elsevier BV; Volume: 91; Issue: 2 Linguagem: Inglês

10.1016/0010-2180(92)90099-b

1556-2921

J.M. Card, F. A. Williams,

Atmospheric chemistry and aerosols

The method of rate-ratio asymptotics is used with reduced chemistry to analyze the flame structure and extinction of an isolated n-heptane droplet burning under quasisteady, spherically symmetrical conditions. The outer transport zones are described by the classical Burke-Schumann solution. The inner reaction zone consists of a thin layer, on the rich side of the flame, where the fuel is consumed, and on the lean side, a broader but still asymptotically thin oxidation layer, where H2 and CO are consumed. Special attention is given to differences in predictions of extinction conditions, caused by different chemical-kinetic approximations in the reduced chemistry, including fuel-chemistry effects through molecules containing more than one carbon atom. From the analysis, extinction diameters for n-heptane droplets are estimated for different pressures and ambient oxygen concentrations. The results show that extinction diameters are extremely sensitive to the number of radicals consumed in breaking down each fuel molecule.