Novel molecularly hybridized polyethylene/silica composite materials: Polymerization of ethylene with supported titanocenes by mesoporous silicates
2000; Wiley; Volume: 38; Issue: S1 Linguagem: Inglês
10.1002/1099-0518(200012)38
ISSN1099-0518
AutoresKeisuke Tajima, Gen Ogawa, Takuzo Aida,
Tópico(s)Polymer Nanocomposites and Properties
ResumoA novel molecularly hybridized polyethylene/silica composite thin film was obtained by the gas-phase polymerization of ethylene with a titanocene-mounted mesoporous silica layer on a mica plate with mesoscopic pores arranged on the film surface. However, the use of titanocene-mounted hexagonal domains of mesoporous silica on a glass plate for the gas-phase polymerization of ethylene resulted in the formation of an islanded polyethylene/silica hybridized material. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 4821–4825, 2000
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