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Modification of acrylonitrile‐butadiene‐styrene terpolymer by graft copolymerization with maleic anhydride in the melt. II. Properties and phase behavior

2004; Wiley; Volume: 91; Issue: 5 Linguagem: Inglês

10.1002/app.13468

1097-4628

Rongrong Qi, Junling Qian, Zhefeng Chen, Xing Jin, Chixing Zhou,

Polymer Nanocomposites and Properties

Abstract The graft copolymerization of maleic anhydride (MAH) onto acrylonitrile‐butadiene‐styrene terpolymer (ABS) using dicumyl peroxide and benzoyl peroxide as the binary initiator and styrene as the comonomer in the molten state was described. The properties and phase morphologies of the modified products (ABS‐ g ‐MAH) were studied. The results indicate that the melt flow index (MFI) of ABS‐ g ‐MAH increases with the increase of MAH content, the initiator concentration, and the screw speed, whereas the MFI decreases with the increase of temperature. The impact strength and the percentage elongation of ABS‐ g ‐MAH both decreased and the tensile strength of ABS‐ g ‐MAH increased slightly as the grafting degree increased. The phase inversion behavior of the modified product was observed by transmission electron microscopy. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2834–2839, 2004