Studies toward the total synthesis of polyoxygenated labdanes: preliminary approaches
1993; Elsevier BV; Volume: 49; Issue: 3 Linguagem: Inglês
10.1016/s0040-4020(01)86264-5
ISSN1464-5416
AutoresDenyse Herlem, J. Kervagoret, Dahai Yu, Françoise Khuong‐Huu, Andrew S. Kende,
Tópico(s)Biological Activity of Diterpenoids and Biflavonoids
ResumoUsing the keto-ester 3 as a starting material, methods are developed for the successive introduction of hydroxy groups at C-6, C-7 and C-8 of a decalin system, as well as for elaboration of a C-9 pentadiene chain in a preliminary approach to the total synthesis of trihydroxylabdadienes.
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