The preparation of molybdenum dialkyldithiocarbamates using oxidative decarbonylation of tricarbonyl(η6-1,3,5-cycloheptatriene)molybdenum
1980; Elsevier BV; Volume: 45; Linguagem: Inglês
10.1016/s0020-1693(00)80108-5
ISSN1873-3255
AutoresDavid A. Brown, W.K. Glass, Khalid S. Jasim,
Tópico(s)Ferrocene Chemistry and Applications
ResumoThe chemical properties of tetraalkylthiuram sulfides are reviewed from the perspective of their interaction with transition and main group metal species. From the available literature, few examples are found of metal ion interactions with the monosulfide. These examples almost invariably lead to metal adducts. The case for the disulfides is more involved and usually leads to dithiocarbamate metal complexes. A few examples of ligand oxidation are also found.
Referência(s)