Artigo Revisado por pares

The preparation of molybdenum dialkyldithiocarbamates using oxidative decarbonylation of tricarbonyl(η6-1,3,5-cycloheptatriene)molybdenum

1980; Elsevier BV; Volume: 45; Linguagem: Inglês

10.1016/s0020-1693(00)80108-5

ISSN

1873-3255

Autores

David A. Brown, W.K. Glass, Khalid S. Jasim,

Tópico(s)

Ferrocene Chemistry and Applications

Resumo

The chemical properties of tetraalkylthiuram sulfides are reviewed from the perspective of their interaction with transition and main group metal species. From the available literature, few examples are found of metal ion interactions with the monosulfide. These examples almost invariably lead to metal adducts. The case for the disulfides is more involved and usually leads to dithiocarbamate metal complexes. A few examples of ligand oxidation are also found.

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