Protodealkylation of bis(aminophenyl) methanes
1986; Elsevier BV; Volume: 27; Issue: 17 Linguagem: Inglês
10.1016/s0040-4039(00)84402-0
ISSN1873-3581
AutoresPeter J. Whitman, Floro F. Frulla, George H. Temme, F. A. Stuber,
Tópico(s)Fluorine in Organic Chemistry
ResumoContrary to earlier reports, the formation of bis(aminophenyl) methanes in the acid-catalyzed condensation of aniline and formaldehyde can result in carbon—carbon bond cleavage proceeding via an ipso protodealkylation mechanism.
Referência(s)