Electrical properties of single-crystal black phosphorus under pressure
1986; Elsevier BV; Volume: 139-140; Linguagem: Inglês
10.1016/0378-4363(86)90606-6
ISSN1873-2127
AutoresYuichi Akahama, S. Endo, Shin‐ichiro Narita,
Tópico(s)Boron and Carbon Nanomaterials Research
ResumoElectrical resistivity measurements under hydrostatic pressure have been carried out on black phosphorus single crystals in a wide range of temperatures. A semiconductor-metal transition, with no structural change, has been observed within the orthorhombic phase; the energy gap of the crystal decreases with the coefficient of −17 meV/kbar and vanishes at 17 kbar. At higher pressures metallic conduction is observed.
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