Portal de Periódicos da CAPES

Synthesis and Structure of a Resonance Stabilized (Trimethylphosphonio)metallapropenide

1988; Wiley; Volume: 27; Issue: 4 Linguagem: Inglês

10.1002/anie.198805871

1521-3773

Dimitrios Lappas, David M. Hoffman, Kirsten Folting, John C. Huffman,

Organophosphorus compounds synthesis

Angewandte Chemie International Edition in EnglishVolume 27, Issue 4 p. 587-589 Communication Synthesis and Structure of a Resonance Stabilized (Trimethylphosphonio)metallapropenide† Dimitrios Lappas, Dimitrios Lappas Department of Chemistry, Harvard University 12 Oxford Street, Cambridge, MA 02 138 (USA)Search for more papers by this authorProf. David M. Hoffman, Corresponding Author Prof. David M. Hoffman Department of Chemistry, Harvard University 12 Oxford Street, Cambridge, MA 02 138 (USA)Department of Chemistry, Harvard University, 12 Oxford Street, Cambridge, MA 02138 (USA)Search for more papers by this authorDr. Kirsten Folting, Dr. Kirsten Folting Molecular Structure Center, Department of Chemistry Indiana University Bloomington, IN 47 405 (USA)Search for more papers by this authorDr. John C. Huffman, Dr. John C. Huffman Molecular Structure Center, Department of Chemistry Indiana University Bloomington, IN 47 405 (USA)Search for more papers by this author Dimitrios Lappas, Dimitrios Lappas Department of Chemistry, Harvard University 12 Oxford Street, Cambridge, MA 02 138 (USA)Search for more papers by this authorProf. David M. Hoffman, Corresponding Author Prof. David M. Hoffman Department of Chemistry, Harvard University 12 Oxford Street, Cambridge, MA 02 138 (USA)Department of Chemistry, Harvard University, 12 Oxford Street, Cambridge, MA 02138 (USA)Search for more papers by this authorDr. Kirsten Folting, Dr. Kirsten Folting Molecular Structure Center, Department of Chemistry Indiana University Bloomington, IN 47 405 (USA)Search for more papers by this authorDr. John C. Huffman, Dr. John C. Huffman Molecular Structure Center, Department of Chemistry Indiana University Bloomington, IN 47 405 (USA)Search for more papers by this author First published: April 1988 https://doi.org/10.1002/anie.198805871Citations: 17 † This work was supported in part by the Donors of the Petroleum Research fund, administered by the American Chemical Society. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The ReO bond in the phosphorus ylide 1 is not involved in its stabilization. This was shown by X-ray analysis and IR spectroscopy. Compound 1 can be isolated as red, cubic crystals after reaction of ethyne with [ReO(PMe3)(CH2SiMe3)3]. Its structure is best described by the two resonance structures 1a and 1b, the latter being the most important one (RCH2SiMe3). Citing Literature Volume27, Issue4April 1988Pages 587-589 RelatedInformation