Aliphatic dicarboxylates with three-dimensional metal–organic frameworks possessing hydrophobic channels
2003; Royal Society of Chemistry; Issue: 8 Linguagem: Inglês
10.1039/b212314m
ISSN1477-9234
AutoresRamanathan Vaidhyanathan, Srinivasan Natarajan, C. N. R. Rao,
Tópico(s)Lanthanide and Transition Metal Complexes
ResumoTwo three-dimensional open-framework metal dicarboxylates possessing channels with a hydrophobic environment have been synthesized. One is a malonate of the formula, [Cd(O2C-CH2-CO2)(H2O)]·H2O, I, and the other a glutarate of the formula [Mn(O2C-(CH2)3-CO2)], II. The three-dimensional structure of I is attained through infinite Cd–O–Cd corner-linkages. On the other hand, II, contains Mn–O–Mn layers cross-linked by MnO6 octahedra and glutarate moieties.
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