Intramolecularly competitive Ireland Claisen rearrangements: Stereoselective synthesis of alkylidene cyclohexenes
1998; Elsevier BV; Volume: 39; Issue: 39 Linguagem: Inglês
10.1016/s0040-4039(98)01525-1
ISSN1873-3581
AutoresXiaowei Zhang, Matthias C. McIntosh,
Tópico(s)Cyclopropane Reaction Mechanisms
ResumoUnsymmetrical bis-allyl silylketene acetals derived from cyclohexenones undergo regio- and stereoselective Ireland Claisen rearrangements to afford alkylidene cyclohexenes in good yield.
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