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Effect of intramolecular exciplex formation upon the photoreactivity of naphthylalkylamines and anthrylalkylamines

1971; Issue: 21 Linguagem: Inglês

10.1039/c29710001385

D. R. G. Brimage, Robert S. Davidson,

Chemical Reaction Mechanisms

Several NN-diethyl-1-naphthylalkylamines and NN-diethyl-9-anthrylalkylamines exhibit intramolecular exciplex formation and as a result reactions typical of the hydrocarbon singlet states, e.g. hydrogen abstraction from tertiary amines and dimerisation, are quenched.